Electron belt-to-σ-hole switch of noncovalently bound iodine(<scp>i</scp>) atoms in dithiocarbamate metal complexes
نویسندگان
چکیده
The nature of metals in the isostructural series dithiocarbamate complexes affects electron belt-to-σ-hole switch noncovalently bound iodine(i) leading to either semicoordination, or halogen bonding.
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ژورنال
عنوان ژورنال: Inorganic chemistry frontiers
سال: 2021
ISSN: ['2052-1553', '2052-1545']
DOI: https://doi.org/10.1039/d1qi00314c